A novel heteropolyoxopalladate structural type has been
discovered: the polyoxo-15-palladate(II) [Pd0.4Na0.6ÃPd15-
P10O50H6.6]
12- (Pd15) has been prepared in a one-pot selfassembly
reaction and characterized by single-crystal XRD,
elemental analysis, IR, TGA, 31P NMR and electrochemistry;
preliminary catalytic studies showed that Pd15 is active as a
catalyst in alcohol oxidation by dioxygen
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